Angelina Jolie's romantic history is as captivating as her onscreen performances Angelina met English actor Johnny Lee Miller while working on the 1995 film hackers the two exchanged vows in a small civil ceremony in 1996 unfortunately their busy schedules kept them apart and they separated just a year later their divorce was finalized in 1999 despite the split Angelina has fondly referred to Johnny as a solid man and a solid friend over the years in 1999 Angelina crossed paths with actor Billy Bob thoron during the filming of pushing tin their connection was intense and they eloped in Las Vegas the following year their marriage became iconic due to their quirky displays of affection including wearing vials of each other's blood however their passionate Union ended in 2003 Angelina's relationship with Brad Pit as perhaps the most well-known they began dating in 2005 and eventually tied the knot in 2014 their Union produced six children and was closely followed by fans and media like however after a tumultuous Journey they legally separated