Brad Pit and Jennifer Aniston were once one of Hollywood's most beloved couples their relationship which spanned from their initial meeting to their eventual divorce was marked by significant Milestones that captured the attention of fans and media alike Jennifer Aniston and Brad Pit first met in 1994 through their managers the couple made their red carpet debut at the Emmy Awards in September 1999 confirming their relationship publicly just a few months later on November 21st 1999 they announced their engagement during a Sting concert in New York City they got married on July 29th 2000 in early January 2005 after nearly 5 years of marriage Aniston and pit announced their separation their joint statement emphasized that the decision was mutual and not due to tabloid speculation on March 25th 2005 Aniston filed for divorce citing irreconcilable differences the divorce was finalized on October 2nd 2005